No. Super Smash Bros. for Wii U (2014) is exclusive to the Wii U console. It cannot run on the original Wii.
Super Smash Bros. Brawl (2008) is the Wii entry. It supports GameCube controllers, Wii Remotes, Classic Controllers, and has Subspace Emissary (story mode). Still playable today—active mod scene (Project M, Brawl Minus) via Homebrew.