No. Major League Baseball Power Pros 2011 on Wii does not support GameCube controllers.
The GameCube controller ports on the original Wii (RVL-001) are only active for GameCube backward compatibility mode and select Wii titles that explicitly enable them (e.g., Super Smash Bros. Brawl, Mario Kart Wii, Mario Strikers Charged). Power Pros 2011 is not one of them.