No. A Nintendo DS Lite charger (model WAP-002 / USG-002) operates at **5V DC / 4.6W (approx. 920mA)**. This is **Extra-Low Voltage (ELV)**, far below the threshold (typically 50V AC / 120V DC) considered dangerous for electric shock under normal conditions.
Bottom line: A genuine, undamaged DS Lite charger poses virtually zero electrocution risk. Treat it with standard electronics care.