No. Madden NFL 12 on Wii does not include Superstar Mode. That mode was exclusive to the Xbox 360 and PlayStation 3 versions (introduced in Madden 10).
EA tailored the Wii release for casual/party play with motion controls:
The Wii's hardware couldn't support the same animation/physics engine as HD consoles. EA built a distinct codebase ("EA Sports Wii Engine") focused on accessibility over simulation depth.
For a career-style mode on Nintendo hardware, you would need Madden NFL 13 on Wii U (which brought back "Connected Careers") or play on Xbox/PlayStation.