General Grievous is NOT a playable character in Star Wars: Episode II - Attack of the Clones on PS2 (or any platform). He does not appear in that game at all (he debuts in Episode III / Clone Wars 2003).
Playable characters: Obi-Wan Kenobi, Anakin Skywalker, Mace Windu (unlockable). Villains: Count Dooku, Jango Fett (bosses). Grievous is absent.
If you want to play as the cyborg general on PS2, Star Wars: Battlefront II (2005) is your best (and only native) option.