You cannot add an “Extras” tab to the PSP’s XMB (XrossMediaBar). The menu structure is hard-coded in the system firmware and cannot be modified by users, themes, or plugins.
/GAME/, /ISO/, /MUSIC/, /VIDEO/, /PICTURE/ to group homebrew, emulators, saves, etc.Stick to folders + a clean custom theme. If you need a radically different UI, run Adrenaline (PSP emulator on Vita) or PPSSPP on PC/phone where front-ends like RetroArch or Pegasus give full library management.