You're trying to solve two completely unrelated tech problems with one solution, and that's why it's not working. The Nintendo DS and Outlook Express 6.0 operate on different planets, technologically speaking.
The original Nintendo DS and DS Lite don't connect to your home Wi-Fi router the way a laptop or phone does. They use a proprietary wireless protocol (802.11b with WEP encryption only) to communicate with the Nintendo Wi-Fi Connection service (discontinued in 2014) or for local multiplayer. They cannot browse the web, check email, or interact with your router's admin panel. If you're trying to get a DS online today, you need a mobile hotspot set to WEP/Open security or a legacy router configuration—modern WPA2/WPA3 networks are invisible to the hardware.
Outlook Express 6.0 shipped with Windows XP (2001). It lacks support for modern authentication (OAuth2), TLS 1.2/1.3 encryption standards required by Gmail, Outlook.com, Yahoo, and virtually every ISP today. It cannot "talk" to a modern router in any meaningful way—routers pass packets, they don't speak email protocols. The incompatibility is between the email client and the mail server's security requirements, not your router.
Stop looking for a magic router setting. Upgrade your email workflow; let the DS be a retro offline gem.